Reactions of 2,3-Dibromonaphthalene-1,4-Dione and Pyridyl Amines: X-ray Structures, DFT Investigations, and Selective Detection of the Hg2+ and Ni2+ Ions
Gunjan Aggrwal, Sunita Salunke-Gawali, Shridhar P. Gejji, Milind Nikalje, Debamitra Chakravarty, Prakash L. Verma, Prajkta Gosavi-Mirkute, Shital Harihar, Mahesh Jadhav and Vedavati G. Puranik
Gunjan Aggrwal,1
Sunita Salunke-Gawali,1*Email
Shridhar P. Gejji,1
ilind Nikalje,1
Debamitra Chakravarty,2
Prakash L. Verma,1
Prajkta Gosavi-Mirkute,1
Shital Harihar,1
Mahesh Jadhav1
Vedavati G. Puranik3
1Department of Chemistry, Savitribai Phule Pune University, Pune 411007, Maharashtra State, India
2Central Instrumentation Facility, Savitribai Phule Pune University, Pune 411007, Maharashtra State, India
3Centre for material Characterization, National Chemical Laboratory, Pashan Road, Maharashtra State, Pune 411008, India
Abstract
In this work, the products formed by the reaction between 2,3-dibromonaphthalene-1,4-dione with (pyridine-2-yl)methanamine and (pyridine-4-yl)methanamine are discussed in detial. The products 2-amino-3-bromonaphthalene-1,4-dione (A) and 2-aminonaphthalene-1,4-dione (B(1)) obtained are characterized through 1H and 13C-NMR, FTIR, mass spectrometry, single-crystal X-ray diffraction experiments, which are in conjunction with wB97X based density functional theory. Compound A can effectively and selectively detect Hg2+ and Ni2+ ions, and proposes a potential mechanism of action.
Publication details
Received: 04 Jan 2021
Revised: 17 Feb 2021
Accepted: 18 Feb 2021
Published online: 18 Feb 2021
Article type:
Research Paper
DOI:
10.30919/es8d427
Volume:
14
Page:
78-93
Citation:
Engineered Science, 2021, 14, 78-93
Permissions:
Copyright
Number of downloads:
2186
Citation Information:
5
Description:
The unusual products formed in the reaction between 2,3-dibromo-1,4-naphthoquninone and pyridylamine....
The unusual products formed in the reaction between 2,3-dibromo-1,4-naphthoquninone and pyridylamines are discussed through experiments combined with theory are presented.
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