Enhancing Dielectric Performance of Poly(vinylidene fluoride) Nanocomposites via Controlled Distribution of Carbon Nanotubes and Barium Titanate Nanoparticle
Jing Wang, Zhicheng Shi, Xin Wang, Xianmin Mai, Runhua Fan, Hu Liu, Xiaojing Wang and Zhanhu Guo
1 School of Materials Science and Engineering, Ocean University of China, Qingdao 266100, China
2 Institute of Marine Materials Science and Engineering, Shanghai Maritime University, Shanghai 201306, China
3 School of Urban Planning and Architecture, Southwest Minzu University, Chengdu 610041, China
4 National Engineering Research Center for Advanced Polymer Processing Technology,Zhengzhou University, Zhengzhou 450002, China
5 School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu, 212003, China
6 Integrated Composites Laboratory (ICL), Department of Chemical & Biomolecular Engineering, University of Tennessee, Knoxville, TN 37996, USA
Abstract
Polymer-based dielectric materials have attracted increasing attention owing to their huge potential applications in modern electronic devices. The dielectric behaviors of polymer composites are greatly determined by the distribution of fillers, thus the clarification of the relationship between the dielectric properties of the composites and the spatial distribution of fillers would be highly favorable for designing novel high-performance dielectrics. Herein, the dielectric performances of ternary composites consisting of barium titanate (BT), carbon nanotube (CNT) and poly(vinylidene fluoride) (PVDF) were investigated. For comparison, the dielectric properties of trilayer composites were also studied. The ternary composites exhibited an ultra-high dielectric constant of 7×103 @10 kHz, but a high loss tangent of 25 @10 kHz. For the trilayer composites, the BT/PVDF outer layers could restrain the development of leakage current, leading to low loss tangent (0.03 @10 kHz) and high breakdown strength. Meanwhile, the trilayer composites also achieved a high dielectric constant of 95 @10 kHz owing to the considerably enhanced polarizations at the filler/matrix and layer/layer interfaces. This research provides important sights into the relationship between the dielectric properties of the composites and the spatial distributions of fillers, which will strongly boost the exploration of high-performance dielectrics.
Publication details
Received: 21 Aug 2018
Revised: 27 Sep 2018
Accepted: 10 Oct 2018
Published online: 11 Oct 2018
Article type:
Research Paper
DOI:
10.30919/es8d759
Volume:
4
Page:
79-86
Citation:
Engineered Science, 2018, 4, 79-86
Permissions:
Copyright
Number of downloads:
6131
Citation Information:
26
Description:
Dielectric performances of ternary composites consisting of barium titanate (BT), carbon nanotube (C....
Dielectric performances of ternary composites consisting of barium titanate (BT), carbon nanotube (CNT) and poly(vinylidene fluoride) (PVDF) were investigated.
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