Significantly Enhanced Ultrathin NiCo-based MOF Nanosheet Electrodes Hybrided with Ti3C2Tx MXene for High Performance Asymmetric Supercapacitor
Yanzhong Wang, Yuexin Liu, Chao Wang, Hu Liu, Jiaoxia Zhang, Jing Lin, Jincheng Fan, Tao Ding, Jong E. Ryu and Zhanhu Guo
1 School of Materials Science and Engineering, North University of China, Taiyuan 030051 China
2 Advanced energy materials and system institute, North University of China, Taiyuan 030051 China
3 Integrated Composites Laboratory (ICL), Department of Chemical & Biomolecular Engineering, University of Tennessee, Knoxville, TN 37966 USA
4 Key Laboratory of Materials Processing and Mold (Zhengzhou University), Ministry of Education, National Engineering Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Zhengzhou, China
5 College of Materials Science and Engineering, Changsha University of Science and Technology, Changsha 410114, China
6 College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, China
7 School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China
8 Department of Mechanical and Aerospace Engineering, North Carolina State University, Raleigh, NC 27695USA
Abstract
In situ synthesis of NiCo based metal-organic framework (MOF) nanosheets and the exfoliation of Ti3C2Tx into isolated nanosheets (MXene), called, NiCo-MOF/Ti3C2Tx hybrid nanosheets, are simultaneously achieved by a facile ultrasonic method. This method can effectively avoid the oxidation and restacking of Ti3C2Tx nanosheets, and also make them uniformly disperse on the surface of NiCo-MOF. The formed NiCo-MOF/Ti3C2Tx hybrid nanosheets achieve a high specific capacitance of 815.2 A g-1 at 1 A g-1. The practical asymmetric supercapacitor (ASC) is fabricated using activated carbon and NiCo-MOF/Ti3C2Tx hybrid nanosheets. The ASC device achieves an energy density of 39.5 Wh kg-1 at a power density of 562.5 W kg-1, and also demonstrates a suitable cycling stability with 82.3 % of capacitance retention after 10000 continuous cycles at 5 A g-1. The enhanced electrochemical property of NiCo-MOF/Ti3C2Tx is attributed to the nanosheet-like and mesoporous structure, high electronic conductivity, and synergistic effect of hybrid electroactive components.
Publication details
Received: 04 Nov 2019
Revised: 21 Dec 2019
Accepted: 06 Jan 2020
Published online: 07 Jan 2020
Article type:
Research Paper
DOI:
10.30919/es8d903
Volume:
9
Page:
50-59
Citation:
Engineered Science, 2020, 9, 50-59
Permissions:
Copyright
Number of downloads:
6565
Citation Information:
32
Description:
Ultrathin NiCo-MOF/Ti3C2Tx demonstrated a capacitance of 815.2 A g-1 and NiCo-MOF/Ti3C2Tx//activated....
Ultrathin NiCo-MOF/Ti3C2Tx demonstrated a capacitance of 815.2 A g-1 and NiCo-MOF/Ti3C2Tx//activated carbon delivered 39.5 Wh kg-1 at 562.5 W kg-1.
This article is cited by 32 publications.
- Dheeraj Kumar Maurya, Vignesh Murugadoss, Zhanhu Guo, Subramania Angaiah. Designing Na2Zn2TeO6-Embedded 3D-Nanofibrous Poly(vinylidenefluoride)-co-hexafluoropropylene-Based Nanohybrid Electrolyte via Electrospinning for Durable Sodium-Ion Capacitors. ACS Applied Energy Materials 2021, 4, 8475, DOI: 10.1021/acsaem.1c01682
- Huayu Liu, Ting Xu, Qidi Liang, Qingshuang Zhao, Dawei Zhao, Chuanling Si. Compressible cellulose nanofibrils/reduced graphene oxide composite carbon aerogel for solid-state supercapacitor. Advanced Composites and Hybrid Materials 2022, 5, 1168, DOI: 10.1007/s42114-022-00427-0
This article is cited by 32 publications.
- Dheeraj Kumar Maurya, Vignesh Murugadoss, Zhanhu Guo, Subramania Angaiah. Designing Na2Zn2TeO6-Embedded 3D-Nanofibrous Poly(vinylidenefluoride)-co-hexafluoropropylene-Based Nanohybrid Electrolyte via Electrospinning for Durable Sodium-Ion Capacitors. ACS Applied Energy Materials 2021, 4, 8475, DOI: 10.1021/acsaem.1c01682
- Huayu Liu, Ting Xu, Qidi Liang, Qingshuang Zhao, Dawei Zhao, Chuanling Si. Compressible cellulose nanofibrils/reduced graphene oxide composite carbon aerogel for solid-state supercapacitor. Advanced Composites and Hybrid Materials 2022, 5, 1168, DOI: 10.1007/s42114-022-00427-0
- Anju Chonat, Shiny Palatty. Enhanced Electrochemical Performance of a Hybrid Supercapacitive Material Based on Ternary Doped Polyaniline/Activated Carbon Composite. Energy & Fuels 2020, 34, 10148, DOI: 10.1021/acs.energyfuels.0c01555
- Xiaoxiao Liu, Qian Shao, Yingming Wang, Yuanpeng Zheng, Hao Song, Junxiang Wang, Hu Liu, Zhanhu Guo. One-pot In Situ Microwave Hydrothermally Grown Zeolitic Imidazolate Framework-8 on ZnIn-Layered Double Oxides toward Enhanced Methylene Blue Photodegradation. Industrial & Engineering Chemistry Research 2020, 59, 16637, DOI: 10.1021/acs.iecr.0c00649
- Mahyar Panahi-Sarmad, Mina Noroozi, Xueliang Xiao, Chul B. Park. Recent Advances in Graphene-Based Polymer Nanocomposites and Foams for Electromagnetic Interference Shielding Applications. Industrial & Engineering Chemistry Research 2022, 61, 1545, DOI: 10.1021/acs.iecr.1c04116
- Lin Wang, Meiyun Zhang, Bin Yang, Jiaojun Tan, Xueyao Ding. Highly Compressible, Thermally Stable, Light-Weight, and Robust Aramid Nanofibers/Ti3AlC2 MXene Composite Aerogel for Sensitive Pressure Sensor. ACS Nano 2020, 14, 10633, DOI: 10.1021/acsnano.0c04888
- En Li, Yamin Pan, Chunfeng Wang, Chuntai Liu, Changyu Shen, Caofeng Pan, Xianhu Liu. Asymmetric Superhydrophobic Textiles for Electromagnetic Interference Shielding, Photothermal Conversion, and Solar Water Evaporation. ACS Applied Materials & Interfaces 2021, 13, 28996, DOI: 10.1021/acsami.1c07976
- Jagadeesh Ramadoss, Arumugam Sonachalam, Mani Govindasamy. Surface Modification Effect on V-Doped Ti3C2Tx as Bifunctional Catalyst Electrodes for Symmetric Supercapacitor and the Hydrogen Evolution Reaction. Energy & Fuels 2023, 37, 17561, DOI: 10.1021/acs.energyfuels.3c03411
- Bing Zhou, Mengjie Su, Daozheng Yang, Gaojie Han, Yuezhan Feng, Bo Wang, Jialu Ma, Jianmin Ma, Chuntai Liu, Changyu Shen. Flexible MXene/Silver Nanowire-Based Transparent Conductive Film with Electromagnetic Interference Shielding and Electro-Photo-Thermal Performance. ACS Applied Materials & Interfaces 2020, 12, 40859, DOI: 10.1021/acsami.0c09020
- Yongpeng Ma, Xiubo Xie, Wenyue Yang, Zhipeng Yu, Xueqin Sun, Yuping Zhang, Xiaoyang Yang, Hideo Kimura, Chuanxin Hou, Zhanhu Guo, Wei Du. Recent advances in transition metal oxides with different dimensions as electrodes for high-performance supercapacitors. Advanced Composites and Hybrid Materials 2021, 4, 906, DOI: 10.1007/s42114-021-00358-2
- Yulian Chen, Yinhui Ouyang, Juan Yang, Liping Zheng, Baobao Chang, Chun Wu, Xiaowei Guo, Gairong Chen, Xianyou Wang. Facile Preparation and Performances of Ni, Co, and Al Layered Double Hydroxides for Application in High-Performance Asymmetric Supercapacitors. ACS Applied Energy Materials 2021, 4, 9384, DOI: 10.1021/acsaem.1c01575
- Mohammad Ashourdan, Abolfazl Semnani, Foroozan Hasanpour, Seyyed Ebrahim Moosavifard. Synthesis of nickel cobalt manganese metal organic framework@high quality graphene composites as novel electrode materials for high performance supercapacitors. Journal of Electroanalytical Chemistry 2021, 895, 115452, DOI: 10.1016/j.jelechem.2021.115452
- Guofeng Li, Ruxing Shen, Shengliang Hu, Bin Wang, Hassan Algadi, Chao Wang. Norbornene-based acid–base blended polymer membranes with low ion exchange capacity for proton exchange membrane fuel cell. Advanced Composites and Hybrid Materials 2022, 5, 2131, DOI: 10.1007/s42114-022-00559-3
- Yize Gong, Song Xie, Xianke Ping, Guishu Li, Junxian He. The influence of overcharge and discharge rate on the thermal safety performance of lithium-ion battery under low air pressure. Ionics 2022, 28, 4653, DOI: 10.1007/s11581-022-04720-2
- Ahmad Husain, Sharique Ahmad, Sara A. Alqarni, Samar J. Almehmadi, Mudasir A. Yatoo, Faiza Habib, Mohd Urooj Shariq, Mujahid Ali khan. Conductive polythiophene/graphitic-carbon nitride nanocomposite for the detection of ethanol mixing in petrol. RSC Advances 2023, 13, 12080, DOI: 10.1039/D3RA00381G
- De Wang, Yanjing Wang, Zhenyu Fu, Yanbin Xu, Li-Xia Yang, Feng Wang, Xiaoling Guo, Wenjuan Sun, Zheng-Long Yang. Cobalt–Nickel Phosphate Composites for the All-Phosphate Asymmetric Supercapacitor and Oxygen Evolution Reaction. ACS Applied Materials & Interfaces 2021, 13, 34507, DOI: 10.1021/acsami.1c04614
- Surbhi Anand, Md. Wasi Ahmad, SK Safdar Hossain, Arup Choudhury. A review on metal-organic framework hybrid-based flexible electrodes for solid-state supercapacitors. Ionics 2023, 29, 4437, DOI: 10.1007/s11581-023-05177-7
- Xiaoyu Zhao, Yingbing Zhang, Yongdan Hou, Zijian Zhao, Yaxin Gong, Yanfei Wang, Huige Wei, Vilas G. Pol. Synergistic effect of tailored 3D/2D Ti3C2Tx/CoS2/C nanostructured composite anode for significantly enhanced Li-ion storage. Advanced Composites and Hybrid Materials 2022, 5, 2988, DOI: 10.1007/s42114-022-00527-x
- Gongwen Tang, Xiangyu Hou, Yi Wang, Zhishan Yan, Tingting Ren, Linrong Ma, Xin Huang, Chengpeng Wang. Hexagonal Boron Nitride/Polyaniline Nanocomposites for Anticorrosive Waterborne Epoxy Coatings. ACS Applied Nano Materials 2022, 5, 361, DOI: 10.1021/acsanm.1c03173
- Daniel Dolz, Ángel Morales-García, Francesc Viñes, Francesc Illas. Exfoliation Energy as a Descriptor of MXenes Synthesizability and Surface Chemical Activity. Nanomaterials 2021, 11, 127, DOI: 10.3390/nano11010127
- Haneesh Saini, Nikitha Srinivasan, Veronika Šedajová, Mandira Majumder, Deepak P. Dubal, Michal Otyepka, Radek Zbořil, Narendra Kurra, Roland A. Fischer, Kolleboyina Jayaramulu. Emerging MXene@Metal–Organic Framework Hybrids: Design Strategies toward Versatile Applications. ACS Nano 2021, 15, 18742, DOI: 10.1021/acsnano.1c06402
- Jayasree A C, Ravichandran R. Electrochemical application of zirconium-based metal-organic framework. Inorganic and Nano-Metal Chemistry 2021, , 1, DOI: 10.1080/24701556.2021.1916527
- Keqi Qu, Zhe Sun, Cai Shi, Weicong Wang, Lidong Xiao, Jiangyang Tian, Zhanhua Huang, Zhanhu Guo. Dual-acting cellulose nanocomposites filled with carbon nanotubes and zeolitic imidazolate framework-67 (ZIF-67)–derived polyhedral porous Co3O4 for symmetric supercapacitors. Advanced Composites and Hybrid Materials 2021, 4, 670, DOI: 10.1007/s42114-021-00293-2
- Xiufang Dong, Xiaolong Zhao, Yanjun Chen, Chao Wang. Investigations about the influence of different carbon matrixes on the electrochemical performance of Na3V2(PO4)3 cathode material for sodium ion batteries. Advanced Composites and Hybrid Materials 2021, 4, 1070, DOI: 10.1007/s42114-021-00319-9
- Elham Chamanehpour, Mohammad Hossein Sayadi, Mahmood Hajiani. A hierarchical graphitic carbon nitride supported by metal–organic framework and copper nanocomposite as a novel bifunctional catalyst with long-term stability for enhanced carbon dioxide photoreduction under solar light irradiation. Advanced Composites and Hybrid Materials 2022, 5, 2461, DOI: 10.1007/s42114-022-00459-6
- Shaobin Li, Tingting Yu, Fengbo Li, Tingting Chen, Li Zhang, Guangning Wang, Jianjiao Xin, Deqing Zhang. Trimetallic Layered Hydroxide Anchored on a Bimetallic NiCo-MOF Derivative as a Self-Supporting Electrode Material for Boosting Supercapacitance. Energy & Fuels 2022, 36, 5492, DOI: 10.1021/acs.energyfuels.2c00813
- Sruthi Rajasekaran, B. Shalini Reghunath, Sunaja Devi K. R., B. Saravanakumar, J. Johnson William, Dephan Pinheiro. Bi Functional Manganese-Pyridine 2,6 Dicarboxylic Acid Metal Organic Frameworks with Reduced Graphene Oxide as an Electroactive Material for Energy Storage and Water Splitting Applications. Journal of The Electrochemical Society 2023, 170, 036505, DOI: 10.1149/1945-7111/acbfe3
- Meena Nemiwal, Verraboina Subbaramaiah, Tian C. Zhang, Dinesh Kumar. Recent advances in visible-light-driven carbon dioxide reduction by metal-organic frameworks. Science of The Total Environment 2021, 762, 144101, DOI: 10.1016/j.scitotenv.2020.144101
- Miaomiao Zhang, Haishun Du, Zhen Wei, Xinyu Zhang, Ruigang Wang. Ultrafast Microwave Synthesis of Nickel-Cobalt Sulfide/Graphene Hybrid Electrodes for High-Performance Asymmetrical Supercapacitors. ACS Applied Energy Materials 2021, 4, 8262, DOI: 10.1021/acsaem.1c01507
- Rui Xue, Hao Guo, Wu Yang, Sheng-Li Huang, Guo-Yu Yang. Cooperation between covalent organic frameworks (COFs) and metal organic frameworks (MOFs): application of COFs-MOFs hybrids. Advanced Composites and Hybrid Materials 2022, 5, 1595, DOI: 10.1007/s42114-022-00432-3
- Irvan Dahlan, Wan Hamizan Wan Mazlan, Andi Mulkan, Haider M. Zwain, Siti Roshayu Hassan, Hamidi Abdul Aziz, Harahsheh Yazeed Ahmad Hasan, Ivar Zekker. Modeling of Batch Organic Dye Adsorption Using Modified Metal‐Organic Framework‐5. Chemical Engineering & Technology 2022, 45, 2080, DOI: 10.1002/ceat.202200042
- Zhuangzhuang Yin, Shihan Qi, Shangkun Deng, Jun Guo, Wei Gan, Peng Chen, Chunsheng Ding, Ziliang Li, Jianrou Li, Yuqing Lu, Ziwei Zhao, Qi Ling, Miao Zhang, Zhaoqi Sun. One-pot Preparation of CoS/CuS Nanocomposite-sensitized TiO2 Nanorod Arrays with Enhanced Photoelectrochemical Performance. Journal of The Electrochemical Society 2022, 169, 076502, DOI: 10.1149/1945-7111/ac7ae0
General Links :
Copyright © 2023 Engineered Science Publisher, All Rights Reserved