Facile One-pot Synthesis of Silver Nanoparticles Supported on α-Zirconium Phosphate Single-Layer Nanosheets

Jingfang Yu 1,2

Luyi Sun 1, Email

Polymer Program, Institute of Materials Science and Department of Chemical & Biomolecular Engineering, University of Connecticut, Storrs, Connecticut 06269, USA

Chemistry Research Laboratory, Department of Chemistry, University of Oxford, 12 Mansfield Road, Oxford, OX1 3TA, UK

Abstract

In this paper, we report a facile one-pot synthesis method to prepare well dispersed silver nanoparticles (NPs) supported on α-zirconium phosphate (α-ZrP) single-layer nanosheets. Silver NPs with a narrow size distribution were reduced on α-ZrP single-layer nanosheet surface due to the electrostatic attractions between the positively charged silver cations and the negatively charged α-ZrP nanosheet support. Three reducing agents: glucose, NaBH4, and tri-sodium citrate were used to reduce Ag+. Transmission electron micrographs show that the reduced silver NPs were well dispersed with a diameter of 18.3 ± 4.4 nm, 48.9 ± 13.8 nm, and 3.5 ± 1.0 nm when reduced by glucose, NaBH4, and tri-sodium citrate, respectively. Overall, we present a facile method to synthesize Ag NPs with various dimensions for widespread applications.

Facile One-pot Synthesis of Silver Nanoparticles Supported on α-Zirconium Phosphate Single-Layer Nanosheets